Superoxide anion (O2-) collisions with CO2 molecules in the energy range 50-950 eV

Abstract

A novel gas-phase molecular scattering study is reported for O2– collisions with CO2 for

impact energies ranging from 50 to 950 eV in the lab frame. The absolute total electron

detachment, relative total and partial ionization cross sections have been measured within this energy range together with the positive ion yields. The primary anionic beam

projectile is produced in a pulsed hollow cathode discharge induced plasma, and its

interactions with the neutral molecular target occur in a gas cell at a well-known constant pressure. For impact energies above 500 eV high mass (m> 44 u) charged complexes

have been detected. With the aid of a theoretical study, using ab initio methods, we propose a mechanism to infer on the formation of these cationic species, which have been assigned to projectile-target stable compounds (CO3+ and CO4+).