(Institución)
 
 

Docu-menta > Fisión Nuclear > Artículos de Fisión Nuclear >

Por favor, use este identificador para citar o enlazar este ítem: http://documenta.ciemat.es/handle/123456789/3271

Título : Analysis of barium retention mechanisms on calcium silicate hydrate phases
Autor : Missana, Tiziana
García-Gutiérrez, Miguel
Mingarro, Manuel
Alonso, Ursula
Palabras clave : CSH
Radioactive waste
Adsorption
Earth alkaline metals
Alkalis
Thermodynamic modelling
Fecha de publicación : ene-2017
Editorial : ELSEVIER
Citación : Tiziana Missana, Miguel García-Gutiérrez, Manuel Mingarro, Ursula Alonso, Analysis of barium retention mechanisms on calcium silicate hydrate phases, Cement and Concrete Research 93 (2017) 8–16.
Resumen : Calcium silicate hydrate (C-S-H) phases mostly contribute to contaminant retention in cement. The adsorption mechanisms of Ba on C-S-H phases with four different Ca/Si ratios were investigated by batch sorption experiments. The sorption kinetics, the effects of the solid to liquid ratio and the presence of alkalis in solution were analysed. Sorption isotherms in a wide range of Ba concentrations (from 10−10 to 1 · 10−1 M) were performed. To understand the underlying retention mechanisms, the effects of Ba adsorption on surface potentials were additionally examined. The main objective of this studywas to develop a sorptionmodel able reproducing not only the Ba sorption behaviour, but also the C-S-H surface potential before and after Ba uptake. The reactions and model parameters selected for satisfying these conditions are discussed in the paper. A three-site model, with weak and strong silanol sites and one exchange site, which satisfactorily fulfils the initial aims, is proposed.
URI : http://dx.doi.org/10.1016/j.cemconres.2016.12.004
http://documenta.ciemat.es/handle/123456789/3271
Aparece en las colecciones: Artículos de Fisión Nuclear

Ficheros en este ítem:

Fichero Descripción Tamaño Formato
97.Missanaetal_2017_CCR_CSH_Ba.pdf1.44 MBAdobe PDFVisualizar/Abrir
View Statistics

Los ítems de Docu-menta están protegidos por una Licencia Creative Commons, con derechos reservados.

 

Información y consultas: documenta@ciemat.es | Documento legal