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Título : | Analysis of barium retention mechanisms on calcium silicate hydrate phases |
Autor : | Missana, Tiziana García-Gutiérrez, Miguel Mingarro, Manuel Alonso, Ursula |
Palabras clave : | CSH Radioactive waste Adsorption Earth alkaline metals Alkalis Thermodynamic modelling |
Fecha de publicación : | ene-2017 |
Editorial : | ELSEVIER |
Citación : | Tiziana Missana, Miguel García-Gutiérrez, Manuel Mingarro, Ursula Alonso, Analysis of barium retention mechanisms on calcium silicate hydrate phases, Cement and Concrete Research 93 (2017) 8–16. |
Resumen : | Calcium silicate hydrate (C-S-H) phases mostly contribute to contaminant retention in cement. The adsorption
mechanisms of Ba on C-S-H phases with four different Ca/Si ratios were investigated by batch sorption experiments.
The sorption kinetics, the effects of the solid to liquid ratio and the presence of alkalis in solution were
analysed. Sorption isotherms in a wide range of Ba concentrations (from 10−10 to 1 · 10−1 M) were performed.
To understand the underlying retention mechanisms, the effects of Ba adsorption on surface potentials were additionally
examined. The main objective of this studywas to develop a sorptionmodel able reproducing not only the Ba sorption behaviour, but also the C-S-H surface potential before and after Ba uptake. The reactions and model parameters selected for satisfying these conditions are discussed in the paper. A three-site model, with weak and strong silanol sites and one exchange site, which satisfactorily fulfils the initial aims, is proposed. |
URI : | http://dx.doi.org/10.1016/j.cemconres.2016.12.004 http://documenta.ciemat.es/handle/123456789/3271 |
Aparece en las colecciones: | Artículos de Fisión Nuclear
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