Investigating the presence of emerging and legacy POPs in European domestic air

Abstract

Presence of organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs) and dechlorane plus (DP) were evaluated in indoor domestic air from four European countries (Belgium, Italy, Spain and Portugal). The main pollutants were hexachlorohexanes (sum of α-, β- and γ-HCH; ΣHCHs) and ΣPCBs (sum of PCB-28, 52, 101, 118, 138, 153 and 180), with median concentrations of 366 and 306 pg/m3 , respectively. By decreasing order came hexachlorobenzene (HCB; 130 pg/m3 ), ΣDDXs (sum of DDTs, DDEs and DDDs; 94.4 pg/m3 ), ΣPBDEs (sum of BDE-17, 28, 47, 66, 99, 100, 153, 154, 183, 206, 207 and 209; 6.08 pg/m3 ) and DP (0.30 pg/m3 ). Lower ΣPCBs and ΣDDXs levels were found at Portuguese homes compared to Belgian, Italian and Spanish households. Italian samples presented also lower ΣHCHs concentrations while Spanish homes revealed higher HCB and BDE-209 indoor air concentrations than those obtained in the other countries. ΣHCHs, ΣDDXs and ΣPBDE levels mirrored lindane, dicofol and Penta-, DecaBDE use, respectively. The influence of building characteristics, surroundings and inhabitants habits on pollutant air concentrations was investigated. Data generated were used to conduct a human exposure assessment for toddlers and adults with median (P50) and upper (P95) concentrations. Results indicated that health risk posed by inhalation of ΣPCBs, ΣHCHs, ΣDDXs, HCB, ΣPBDEs and DP were 2 to 5 orders of magnitude lower than oral Reference Dose (RfD) values, and 90 (PCB-28) and 12 (γ-HCH) times lower than Minimal Risk Levels (MRLs) for toddlers at the worst case scenario